In recent years, fresh milk, soy milk, and many fruit juice beverages and condiments packed in plastic films have appeared in the market. Since milk, soy milk, beverages, etc. are fresh drinks, the requirements for hygiene and temperature are very strict. Therefore, there are special requirements for h-bag printing, which makes printing different from milk and beverage packaging films. Other printing technical features.
The characteristics of liquid soft plastic packaging film
The film material used for liquid soft plastic packaging film is mainly polyethylene (PE) co-extruded film, which must meet the requirements of packaging printing, processing, storage and transportation and hygiene. From the perspective of the appearance of the film, it can be divided into three categories: soft white PE film, black and white coextrusion PE film, hard high temperature cooking PE film.
The soft white PE film is mainly used for packaging of simple liquids such as milk, soy sauce and vinegar. The co-extrusion blown film masterbatch consists of LDPE, LLDPE and milky white material. The performance of the membrane, the barrier performance is relatively poor, sterilization temperature does not exceed 90 °C, the shelf life is relatively short; generally used in manual or low-speed filling equipment. Such as low-grade milk packaging, the general shelf life of up to three days, the nearest sale.
The black-and-white films are mostly three-layered, with a maximum of five layers. When the film is blown, the increased intermediate layer is a coextruded barrier masterbatch. The black masterbatch of the heat-sealing inner layer blocks light and blocks ultraviolet light. Due to the presence of an intermediate barrier layer and a masterbatch consisting of E-VA, eval, etc., the shelf life of the contents is longer and can be maintained for more than 30 days. However, there are some three-layer co-extruded black and white films on the market. The middle layer is not It is composed of a barrier masterbatch, so this black and white film is also in the first category. Among the three types of films, the black and white film is the most unfavorable to the printing operation. When the black and white film is formed into a film, the amount of the slip agent and the brightener contained therein is the largest, so as to meet the requirement that the black and white film has a small coefficient of friction on the high-speed automatic filling machine, and the added oily substance is extremely unfavorable to the color printing process and greatly reduces the Ink adhesion properties. In most high-speed automatic filling machines, a sterilization system with direct hot hydrogen peroxide is used to sterilize the packaging film. In this case, it is necessary to pay attention to the influence of the sterilization conditions on the ink layer because some of the pigments in the ink have poor oxidation resistance. Tests have shown that hydrogen peroxide oxidation increases significantly with increasing temperature. Therefore, color printing manufacturers must be clear about the customer's post-processing conditions when providing packaging materials.
The rigid high-temperature cooking PE film is mainly used for milk beverages such as yoghurt, soy milk and so on. When the contents are sterilized after filling, an ultra-high temperature sterilization process is used. The rigid co-extruded PE film uses HDPE masterbatch as the main component, adding some LDPE and colored masterbatch. Therefore, the rigid PE film has good high-temperature resistance and can meet the requirements of ultra-high temperature sterilization. Due to the pressure difference during sterilization, the "bulging bag" phenomenon is easy to occur. Therefore, it is required that the hard PE film not only has a good heat sealing strength, but also the tensile strength performance of the film is better, and color printing manufacturers generally use "three meters throw high" or "One foot on foot" test effect.
Printing ink for liquid soft plastic packaging film
Liquid packaging films such as milk and beverages are usually printed by means of surface printing. Most of them are polyamides or modified into binders. These inks were first developed in gravure printing inks in China, and the production process is relatively mature and complete. This type of ink is suitable for polyethylene, polypropylene film, ink layer adhesion fastness, good luster; but the polyamide type ink Pu h has poor water resistance, not resistant to grease, not resistant to freezing and other performance defects. Printing of this type of ink in high-temperature summers tends to produce stickiness and softening, and freeze-up occurs during low-temperature winter printing.
Liquid packaging in the post-processing of filling, distribution, storage, etc., must be sterilized by high temperature or frozen, so the inherent defects of the polyamide type table printing ink can not meet the requirements of liquid packaging, production of liquid packaging manufacturers of color printing Must be for different types of co-extruded PE film, non-polyamide type of printing ink, the most suitable liquid package ink in the market is polyester and modified products, single-liquid type and two-liquid reaction type Ink.
(I) Safety and health
Since milk and beverages are for human consumption, packaging films, printing inks, etc. should also meet the hygienic standards for packaging materials and food packaging regulations. Therefore, the inks used for printing should be non-toxic, odorless, and have less residual solvents. Does not contain toxic heavy metals and other requirements. So as not to contaminate milk and drinks, and harm the health of consumers.
According to the above requirements for ink performance, it is necessary to select an ink with superior performance. The general printing is the use of two-component polyurethane type surface printing ink, and after the ink is printed, the gloss oil treatment is performed, the cost is relatively high and the process is cumbersome. At present, the more widely used and better quality is Chao Lifu 313A type surface printing ink and Chaolifu 314 type surface printing ink produced by Zhejiang New Oriental Ink Group Co., Ltd. It does not need to be separately treated with a varnish, but only in the printing ink. The addition of a quantitative hardener, after curing for 24 hours after printing, achieves both resistance to boiling, to hydrogen peroxide treatment, and to abrasion.
These two kinds of inks are special printing inks designed for milk and beverage packaging films, and have good affinity with polyethylene film, good glossiness of ink layer, high attachment fastness, heat resistance, oil resistance, and resistance Water-based properties are also excellent; it can be said to be ideal for liquid packaging film printing inks such as milk and beverages. Chao Lifu 313A ink is an alcohol-soluble polyamide ink that can withstand boiling below 100°C and can withstand hydrogen peroxide sterilization below 60%. Chao Lifu 314 printing ink is a two-reaction reactive polyurethane-modified ink, capable of resistance to 121 °C / 40 minutes retort sterilization, can withstand 80 °C, a concentration of 35% hydrogen peroxide sterilization. According to the oxidation resistance test of Chaolifu 314 two-liquid reactive ink, the printed film after 24 hours of aging was soaked in hydrogen peroxide solution at a temperature of 45°C to 50°C and a concentration of 35% for about 15 minutes. The ink has good adhesion and basically no discoloration. It can fully meet the requirements of liquid packaging such as milk and beverages.
(II) Adjustment and control of ink properties
1. The viscosity of the ink
Viscosity is the most important control index in ink applications. It directly affects the transfer performance of inks and the quality of prints. Therefore, the control of ink viscosity in the printing process is very important, generally controlled between 15-20 seconds. Ink viscosity is too low, it is easy to cause some pinholes, hair imaginary, and ink spread in the graphic and text; conversely, if the viscosity is too high, the ink's h-transfer performance is relatively poor, and it is easy to produce stencil, dry-printing phenomenon, and large-area solid ink. Faults such as broken lines.
2. Dryness of ink
The drying performance of the ink is also one of the important indicators to measure the quality and performance of the ink. Controlling the drying performance of the ink is a necessary condition for obtaining a good printing effect. The drying speed of the ink is too fast, and it is prone to dry printing failure. However, the drying speed of the ink is too slow, and the problem of sticky printing on the back side of the printed matter occurs. The general principle of choosing the ink drying speed is that under the existing conditions of the printing machine, the ink should be able to be fully dried before entering the next printing color and before rewinding, but it cannot be dried on the printing plate. The ink used for the printing and packaging film is a solvent type ink, and the drying property mainly depends on the volatilization rate of the solvent. Therefore, in actual production, the ratio of the solvent must be strictly controlled, and an appropriate amount of slow-drying can be added to the ink according to the actual situation. Solvent or quick-drying solvent to adjust the drying speed of the ink to ensure that the ink can be fully dried to prevent “dry-off†phenomenon. When using Chao Lifu 314 dual-liquid reactive inks, the ink viscosity is generally controlled at about 15 seconds under the normal printing speed of 80/min. According to practice, the basic ratio of the mixed solvent used is : Butanone: Toluene: Butyl ester = 4:3.5:2.5. This ensures better print quality.
Precautions during printing of liquid soft plastic packaging film
(a) Choose the right material.
In actual production, appropriate printing [films and printing inks] should be selected according to the specific conditions of filling speed, sterilization conditions, and product shelf life of the automatic filling machine, and the printing process parameters should be adjusted and controlled according to the actual situation, and the process should be standardized. The process ensures the printing quality of the film. Polyamide watch ink because of its water resistance, oil resistance is not good, liquid ink can not generally be selected; polyurethane inks are also different types, the selection must be targeted, New Oriental Chao Li 313A ink is generally used only for soft Coextruded PE film, and 314 is suitable for a variety of coextruded PE film. The co-extruded PE film used by the color printing manufacturers is generally manufactured by the manufacturers themselves, and the technical level is not the same. Therefore, it is necessary to grasp the selection of the masterbatch. It is advisable to use the masterbatch that does not contain the slip agent; the PE film used passes through After EDM treatment, the surface energy must be at least 40 dyne, preferably more than 42 dyne.
(b) The customer's post-processing conditions or test standards. The color printing manufacturers can only achieve a targeted and well-informed knowledge if they fully understand the conditions of the food manufacturers during filling and the subsequent processing techniques, and even the detailed requirements for liquid packaging in the market. The main points of attention include: filling speed, sterilization conditions, length of shelf life, preservation requirements, etc.
(C) the requirements of the printing process. In order to ensure the printing quality of the liquid packaging film, it is also necessary to pay attention to the control of printing tension, printing pressure, printing speed and drying temperature during the printing process, formulate a set of stable and reliable process standards, standardize the process flow, and ensure the scale production. The smooth progress. In addition, the overall quality of printing workers, the technical information provided by ink manufacturers, the quality of thinner materials, and the changes in the workshop environment are also factors that cannot be ignored.
(D) control the printing environment. The change of temperature and humidity in the printing shop has a certain impact on the properties of the substrate materials and inks. Too dry environments can cause static electricity in the film and cause difficulties in printing. Too much humidity in the environment can result in insufficient drying of the ink and affect the firmness of the ink layer. Therefore, the ambient temperature and relative humidity in the printing shop should be strictly controlled, as far as possible to maintain a relatively constant, and to ensure good ventilation, in order to reduce the incidence of printing failures. In general, the temperature in the workshop is controlled between 18°C ​​and 25°C, and the relative humidity is preferably between 60% and 70%.
(e) Do a good job of inspection of finished products. Customer satisfaction is the highest criterion and final desire of each printing company, so it is necessary to ensure that qualified products are delivered to customers. This will not only satisfy customers, but also safeguard the company's image and reputation. This is the basis for maintaining and developing good customer relationships.
In the production process of liquid packs, the changing of the film is relatively frequent, and the performance of the film is likely to vary. The liquid pack uses a small amount of ink, and the long-term use of the old ink printing may also bring about a decline in the performance of the ink. Therefore, the liquid pack may be produced. Many factors are changing. Color printing companies can work out a set of suitable testing standards for finished products by simulating the conditions of use of customers, so as to ensure that unqualified products do not leave the factory and avoid unnecessary losses.
The characteristics of liquid soft plastic packaging film
The film material used for liquid soft plastic packaging film is mainly polyethylene (PE) co-extruded film, which must meet the requirements of packaging printing, processing, storage and transportation and hygiene. From the perspective of the appearance of the film, it can be divided into three categories: soft white PE film, black and white coextrusion PE film, hard high temperature cooking PE film.
The soft white PE film is mainly used for packaging of simple liquids such as milk, soy sauce and vinegar. The co-extrusion blown film masterbatch consists of LDPE, LLDPE and milky white material. The performance of the membrane, the barrier performance is relatively poor, sterilization temperature does not exceed 90 °C, the shelf life is relatively short; generally used in manual or low-speed filling equipment. Such as low-grade milk packaging, the general shelf life of up to three days, the nearest sale.
The black-and-white films are mostly three-layered, with a maximum of five layers. When the film is blown, the increased intermediate layer is a coextruded barrier masterbatch. The black masterbatch of the heat-sealing inner layer blocks light and blocks ultraviolet light. Due to the presence of an intermediate barrier layer and a masterbatch consisting of E-VA, eval, etc., the shelf life of the contents is longer and can be maintained for more than 30 days. However, there are some three-layer co-extruded black and white films on the market. The middle layer is not It is composed of a barrier masterbatch, so this black and white film is also in the first category. Among the three types of films, the black and white film is the most unfavorable to the printing operation. When the black and white film is formed into a film, the amount of the slip agent and the brightener contained therein is the largest, so as to meet the requirement that the black and white film has a small coefficient of friction on the high-speed automatic filling machine, and the added oily substance is extremely unfavorable to the color printing process and greatly reduces the Ink adhesion properties. In most high-speed automatic filling machines, a sterilization system with direct hot hydrogen peroxide is used to sterilize the packaging film. In this case, it is necessary to pay attention to the influence of the sterilization conditions on the ink layer because some of the pigments in the ink have poor oxidation resistance. Tests have shown that hydrogen peroxide oxidation increases significantly with increasing temperature. Therefore, color printing manufacturers must be clear about the customer's post-processing conditions when providing packaging materials.
The rigid high-temperature cooking PE film is mainly used for milk beverages such as yoghurt, soy milk and so on. When the contents are sterilized after filling, an ultra-high temperature sterilization process is used. The rigid co-extruded PE film uses HDPE masterbatch as the main component, adding some LDPE and colored masterbatch. Therefore, the rigid PE film has good high-temperature resistance and can meet the requirements of ultra-high temperature sterilization. Due to the pressure difference during sterilization, the "bulging bag" phenomenon is easy to occur. Therefore, it is required that the hard PE film not only has a good heat sealing strength, but also the tensile strength performance of the film is better, and color printing manufacturers generally use "three meters throw high" or "One foot on foot" test effect.
Printing ink for liquid soft plastic packaging film
Liquid packaging films such as milk and beverages are usually printed by means of surface printing. Most of them are polyamides or modified into binders. These inks were first developed in gravure printing inks in China, and the production process is relatively mature and complete. This type of ink is suitable for polyethylene, polypropylene film, ink layer adhesion fastness, good luster; but the polyamide type ink Pu h has poor water resistance, not resistant to grease, not resistant to freezing and other performance defects. Printing of this type of ink in high-temperature summers tends to produce stickiness and softening, and freeze-up occurs during low-temperature winter printing.
Liquid packaging in the post-processing of filling, distribution, storage, etc., must be sterilized by high temperature or frozen, so the inherent defects of the polyamide type table printing ink can not meet the requirements of liquid packaging, production of liquid packaging manufacturers of color printing Must be for different types of co-extruded PE film, non-polyamide type of printing ink, the most suitable liquid package ink in the market is polyester and modified products, single-liquid type and two-liquid reaction type Ink.
(I) Safety and health
Since milk and beverages are for human consumption, packaging films, printing inks, etc. should also meet the hygienic standards for packaging materials and food packaging regulations. Therefore, the inks used for printing should be non-toxic, odorless, and have less residual solvents. Does not contain toxic heavy metals and other requirements. So as not to contaminate milk and drinks, and harm the health of consumers.
According to the above requirements for ink performance, it is necessary to select an ink with superior performance. The general printing is the use of two-component polyurethane type surface printing ink, and after the ink is printed, the gloss oil treatment is performed, the cost is relatively high and the process is cumbersome. At present, the more widely used and better quality is Chao Lifu 313A type surface printing ink and Chaolifu 314 type surface printing ink produced by Zhejiang New Oriental Ink Group Co., Ltd. It does not need to be separately treated with a varnish, but only in the printing ink. The addition of a quantitative hardener, after curing for 24 hours after printing, achieves both resistance to boiling, to hydrogen peroxide treatment, and to abrasion.
These two kinds of inks are special printing inks designed for milk and beverage packaging films, and have good affinity with polyethylene film, good glossiness of ink layer, high attachment fastness, heat resistance, oil resistance, and resistance Water-based properties are also excellent; it can be said to be ideal for liquid packaging film printing inks such as milk and beverages. Chao Lifu 313A ink is an alcohol-soluble polyamide ink that can withstand boiling below 100°C and can withstand hydrogen peroxide sterilization below 60%. Chao Lifu 314 printing ink is a two-reaction reactive polyurethane-modified ink, capable of resistance to 121 °C / 40 minutes retort sterilization, can withstand 80 °C, a concentration of 35% hydrogen peroxide sterilization. According to the oxidation resistance test of Chaolifu 314 two-liquid reactive ink, the printed film after 24 hours of aging was soaked in hydrogen peroxide solution at a temperature of 45°C to 50°C and a concentration of 35% for about 15 minutes. The ink has good adhesion and basically no discoloration. It can fully meet the requirements of liquid packaging such as milk and beverages.
(II) Adjustment and control of ink properties
1. The viscosity of the ink
Viscosity is the most important control index in ink applications. It directly affects the transfer performance of inks and the quality of prints. Therefore, the control of ink viscosity in the printing process is very important, generally controlled between 15-20 seconds. Ink viscosity is too low, it is easy to cause some pinholes, hair imaginary, and ink spread in the graphic and text; conversely, if the viscosity is too high, the ink's h-transfer performance is relatively poor, and it is easy to produce stencil, dry-printing phenomenon, and large-area solid ink. Faults such as broken lines.
2. Dryness of ink
The drying performance of the ink is also one of the important indicators to measure the quality and performance of the ink. Controlling the drying performance of the ink is a necessary condition for obtaining a good printing effect. The drying speed of the ink is too fast, and it is prone to dry printing failure. However, the drying speed of the ink is too slow, and the problem of sticky printing on the back side of the printed matter occurs. The general principle of choosing the ink drying speed is that under the existing conditions of the printing machine, the ink should be able to be fully dried before entering the next printing color and before rewinding, but it cannot be dried on the printing plate. The ink used for the printing and packaging film is a solvent type ink, and the drying property mainly depends on the volatilization rate of the solvent. Therefore, in actual production, the ratio of the solvent must be strictly controlled, and an appropriate amount of slow-drying can be added to the ink according to the actual situation. Solvent or quick-drying solvent to adjust the drying speed of the ink to ensure that the ink can be fully dried to prevent “dry-off†phenomenon. When using Chao Lifu 314 dual-liquid reactive inks, the ink viscosity is generally controlled at about 15 seconds under the normal printing speed of 80/min. According to practice, the basic ratio of the mixed solvent used is : Butanone: Toluene: Butyl ester = 4:3.5:2.5. This ensures better print quality.
Precautions during printing of liquid soft plastic packaging film
(a) Choose the right material.
In actual production, appropriate printing [films and printing inks] should be selected according to the specific conditions of filling speed, sterilization conditions, and product shelf life of the automatic filling machine, and the printing process parameters should be adjusted and controlled according to the actual situation, and the process should be standardized. The process ensures the printing quality of the film. Polyamide watch ink because of its water resistance, oil resistance is not good, liquid ink can not generally be selected; polyurethane inks are also different types, the selection must be targeted, New Oriental Chao Li 313A ink is generally used only for soft Coextruded PE film, and 314 is suitable for a variety of coextruded PE film. The co-extruded PE film used by the color printing manufacturers is generally manufactured by the manufacturers themselves, and the technical level is not the same. Therefore, it is necessary to grasp the selection of the masterbatch. It is advisable to use the masterbatch that does not contain the slip agent; the PE film used passes through After EDM treatment, the surface energy must be at least 40 dyne, preferably more than 42 dyne.
(b) The customer's post-processing conditions or test standards. The color printing manufacturers can only achieve a targeted and well-informed knowledge if they fully understand the conditions of the food manufacturers during filling and the subsequent processing techniques, and even the detailed requirements for liquid packaging in the market. The main points of attention include: filling speed, sterilization conditions, length of shelf life, preservation requirements, etc.
(C) the requirements of the printing process. In order to ensure the printing quality of the liquid packaging film, it is also necessary to pay attention to the control of printing tension, printing pressure, printing speed and drying temperature during the printing process, formulate a set of stable and reliable process standards, standardize the process flow, and ensure the scale production. The smooth progress. In addition, the overall quality of printing workers, the technical information provided by ink manufacturers, the quality of thinner materials, and the changes in the workshop environment are also factors that cannot be ignored.
(D) control the printing environment. The change of temperature and humidity in the printing shop has a certain impact on the properties of the substrate materials and inks. Too dry environments can cause static electricity in the film and cause difficulties in printing. Too much humidity in the environment can result in insufficient drying of the ink and affect the firmness of the ink layer. Therefore, the ambient temperature and relative humidity in the printing shop should be strictly controlled, as far as possible to maintain a relatively constant, and to ensure good ventilation, in order to reduce the incidence of printing failures. In general, the temperature in the workshop is controlled between 18°C ​​and 25°C, and the relative humidity is preferably between 60% and 70%.
(e) Do a good job of inspection of finished products. Customer satisfaction is the highest criterion and final desire of each printing company, so it is necessary to ensure that qualified products are delivered to customers. This will not only satisfy customers, but also safeguard the company's image and reputation. This is the basis for maintaining and developing good customer relationships.
In the production process of liquid packs, the changing of the film is relatively frequent, and the performance of the film is likely to vary. The liquid pack uses a small amount of ink, and the long-term use of the old ink printing may also bring about a decline in the performance of the ink. Therefore, the liquid pack may be produced. Many factors are changing. Color printing companies can work out a set of suitable testing standards for finished products by simulating the conditions of use of customers, so as to ensure that unqualified products do not leave the factory and avoid unnecessary losses.
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